| Secretary of State | Robert Smith, 1809 James Monroe, 1811 |
| Secretary of the Treasury | Albert Gallatin (Cont.) George W. Campbell, 1814 Alexander J. Dallas, 1814 William H. Crawford, 1816 |
| Secretary of War | William Eustis, 1809 John Armstrong, 1813 James Monroe, 1814 William H. Crawford, 1815 |
| Attorney General | Caesar A. Rodney (Cont.) William Pinckney, 1811 Richard Rush, 1814 |
| Secretary of the Navy | Paul Hamilton, 1809 William Jones, 1813 B. W. Crowninshield, 1814 |